Here’s to hydrogen: Australia is missing the potential of solar fuels

Many times in human history governments have tried to write policies based around future technologies and missed identifying the transformational keys. In the 1970s, for example, few if any horizon-scanning policies on communications predicted the internet or mobile phones. Yet scientists are increasingly…

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It’s time to take solar transport fuels a lot more seriously. National Renewable Energy Lab

Many times in human history governments have tried to write policies based around future technologies and missed identifying the transformational keys. In the 1970s, for example, few if any horizon-scanning policies on communications predicted the internet or mobile phones. Yet scientists are increasingly unified in the need to develop new technologies to address the critical problems now facing us in fields such as energy and climate change.

The Federal Government’s Energy White Paper 2012 aims to chart the nation’s course towards greater energy security while meeting our ethical and legal obligations to mitigate climate change. Clouding the vision, though, is an underlying agenda to profitably privatise electricity services and export coal, natural gas and uranium.

In such a fraught context the tensions of leadership are tersely captured in the report’s conclusion: “Australia’s energy technology and fuel mix should be determined by the market.”

Australia, you’re missing a clean energy source

The document repeatedly makes the case that Australian’s energy sector is transitioning towards clean energy (zero greenhouse gas emissions) sources. But the timetable for this to happen seems seriously out of joint, not only with with the urgency of the climate change problem, but with research in revolutionary areas of clean energy technology.

The report plans for clean energy technologies providing around 40% of Australia’s electricity generation by 2035 and up to 85% by 2050. Large scale solar would contribute 16%, wind energy and household PV 13% each, and hydroelectricity and bioelectricity 5%.

When the report plans for a transformation in transportation fuels by 2050, it mentions biodiesel 13%, natural gas 12%, bio-derived jet fuel 8% and synthetic diesels 2%.

More than 60% of our energy needs involve fuel for planes, ships, trucks, heavy equipment and machinery. mojoey/flickr

Yet it does not discuss molecular solar fuels (the storage of solar energy in non-biological chemical bonds such as hydrogen and its molecular complexes for example with CO2).

Hydrogen’s greatest advantage as a fuel may be in the area of transportation. More than 60% of our energy needs, for example, involve fuel for planes, ships, trucks, heavy equipment and machinery. It has been recognised that providing cheap access to large amounts of hydrogen could significantly enhance our prospects of addressing the critical energy and climate change problems of our time: hydrogen has a high energy density, is not a greenhouse gas and when burnt creates fresh water.

How do solar fuels work?

Scientists have been splitting water molecules to create hydrogen gas for decades, but the process has required electricity or (if solar energy was used) needed expensive rare earth metals such as platinum.

Some of the best prospects of using hydrogen as a fuel involve not condensing it as a gas or liquefying it (which are energy expensive) but storing it in metal hydrides. This leads to the prospect that one day buildings will not only be using sunlight to split water as a source of their hydrogen fuel and part of their contribution to our protective atmosphere (along with absorption of carbon dioxide), but storing it in their structure.

Many energy policy makers and funding agencies (including those in Australia) consider that solar energy research and development is all about photo-voltaics (PV); that is, capturing solar photons for transmission to the electricity grid, batteries or thermal storage. Yet cyanobacteria and plants have been storing solar energy in chemical bonds for several billion years and the scientific challenge of improving upon that whole process is perhaps the most important of our time.

Anhydrous ammonia is another potential solar fuel (derived from atmospheric nitrogen). Mostly used as a fertiliser, ammonia is easy to transport and store and can be burned in an internal combustion engine with few modifications and no greenhouse gas emissions. Yet the chemistry challenges in building such a wholly integrated artificial photosynthetic system are complex and expensive to address.

They’re on to it overseas

The US Department of Energy is increasing funding for fuel cells and “hydrogen vehicle systems”. The US National Hydrogen Association and US Fuel Cell Council (USFCC) have set a goal of getting the full $132m additional funding.

The US has seen the potential of hydrogen. waltarrrr/flickr

In the US, a cluster of hydrogen filling stations operates in New York State (including one at JFK Airport operated by Shell, the US Department of Energy and General Motors), making driving between them feasible.

Europe has been supportive of efforts to extend solar hydrogen fuel research and deployment. The European Fuel Cell and Hydrogen Joint Undertaking (FCH JTI) has €1 billion funding available from the European Commission, to spend on transport and refuelling infrastructure, stationary power generation and combined heat and power; portable applications or small utility vehicles); hydrogen production and distribution; training regulators and developing a lifecycle assessment framework.

Fifty-four universities and research institutes form a related research grouping called N.ERGHY. The aim is to put technologies on the market two to five years earlier than they would do without the financial support.

What’s stopping Australia?

It is not only a lack of understanding of the molecular mechanisms involved in artificial photosynthesis' immensely complex light capture, electron transfer, catalysis and reduction processes that is holding back solar fuels development. Public policy discussion also lacks appreciation of the long-term economic and environmental importance of solar fuels.

Developing clean energy transportation fuels is critical for our economic stability and environmental sustainability. The possibility of electric vehicles with rechargeable batteries is touted (for example in the Energy White Paper) as central to the clean energy transition in the transport sector, but if the electricity is obtained from the grid those vehicles will still contribute to atmospheric greenhouse emissions. There are also major problems with storage and life cycle usage of batteries.

Australia has particular advantages that could easily make us a leader in solar fuels research and development. Our continent has the highest average solar radiation per square metre of any continent. The Clean Energy Finance Corporation is stated to have $10 billion and ARENA $3.2 billion and the Clean Energy Program $1.2 billion to invest in clean energy technologies. Surely a feasible case can be made for such schemes to include funding assisting a broad consortium focused on deployment of a solar fuels prototype?

Large and well funded research projects on molecular solar fuels have now commenced in most developed nations. These are led by organisations such as the US Joint Center on Artificial Photosynthesis (JCAP) involving Caltech and Berkeley, the Solar H2 network in Europe and the Solar Fuels Institute (SOFI) coordinated by Northwestern University in the US.

It is high time Australia set up its own dedicated national solar fuels project.

Join the conversation

40 Comments sorted by

  1. John Newlands

    tree changer

    This viewpoint has the support of the presenters of Top Gear after they attempted a long distance drive in battery cars. I think there are two key issues; the affordability of the hydrogen based alternative fuel and the affordability of the infrastructure and vehicles. Liquid hydrogen in fuel cell cars seems to fail on both counts.

    I'll go further and suggest numbers. Running this solar hydrogen car should cost less than 10c a kilometre in fuel and the sticker price of the vehicles should start…

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  3. Peter Campbell

    Scientist (researcherid B-7232-2008)

    battery life cycle was mentioned as a problem yet I have been driving DIY converted battery electric car for almost 4 years at 10,000km/yr and their is no sign that my battery is not as good as the day I bought it. Relatively cheap, good quality LiFePO4 cells from China are the enabling technology. I will be disappointed and surprised if I do not get a decade of use from my battery. If I can make an electric car with very respectable performance without the resources of a big vehicle company then the technical limitations cannot be very great!

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    1. John Bailo

      logged in via Facebook

      In reply to Peter Campbell

      So can you go 720 miles on a battery charge?

      And does it take 5 minutes to recharge?

      With energy from the sun?

      Next!!!

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    2. David Boxall

      logged in via Facebook

      In reply to Peter Campbell

      John Bailo: "... does it take 5 minutes to recharge?" Living in regional Australia, electric vehicles puzzle me. Given their limitations, are they worth buying? Wouldn't it be easier to take a bus or taxi or - gasp - walk?

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    3. Peter Campbell

      Scientist (researcherid B-7232-2008)

      In reply to John Bailo

      We are a two car family. One car never left town and it was that petrol car that was replaced with a battery car. The range is ample for our normal urban transport: commuting, shopping, picking up kids from various places, going out in the evening etc.
      Yes to energy from the sun. That is the whole point as far as I am concerned: I purchase sufficient GreenPower (really retirement of Renewable Energy Certificates) to run the car and house. This is a voluntary action which means additional renewable…

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    4. Alex Cannara

      logged in via LinkedIn

      In reply to Peter Campbell

      Peter, don't worry about the range fearers. The technology of mobile storage is in its early years, with many, many R&D efforts afoot. Even battery=-swap in metro areas will make the current systems work fine. Tesla here is already committing to charging stations.

      And, if one worries in rural areas, get a hybrid. The advantages of electric drive, even with a small battery, are huge in reducing emissions overall.

      Electric drive with some storage allows regenerative braking to add 15% to…

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    5. Peter Campbell

      Scientist (researcherid B-7232-2008)

      In reply to Alex Cannara

      Only 2/3 of the petrol wasted?! You must have a very good petrol engine. I thought 25% efficient was more usual, with 75% as waste heat. An interesting claim I heard was that refining a litre of petrol uses 1.5kWh of electricity.
      I agree that for rural areas, or where someone wants one car to fulfil all functions, a series hybrid like the Volt would be appropriate. It is a proper electric car that can be charged from the wall. It has enough battery to use very little petrol in urban use but the petrol generator comes on automatically to prevent the battery falling below some minimum charge level on longer trips. More complex and expensive but practical.

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    6. Alex Cannara

      logged in via LinkedIn

      In reply to Peter Campbell

      I was being generous, Peter. most folks up here aren't even ware that some of their $ go out the pipe, so 3/4 might cause seizures.
      ;]
      Another way to look at the watse is that 1 gallon of gasoline requires ~170,000lbs of vegetable matter to be covered nad processed underground for ~700,000 years before we can drill for it.

      It's all very ridiculous, and not news at all.

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    7. Robert McDougall

      Small Business Owner

      In reply to John Bailo

      still early days but the technology is developing, check again in another 5 years. Nothing stopping you from having two batteries, one to charge and one to use, as in mobile phones.

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  4. David Leigh

    logged in via Facebook

    Ten years ago, I made a short documentary on Hydrogen Fuel Cell bases. It opened my eyes to a possible change in thinking, away from hydrocarbon fuels. Every major city in Australia had at lease 3 buses running and on every route, to test the capabilities. I interviewed a driver and heard that the performance, whilst slightly less than a diesel powered bus, was good under all conditions. I interviewed the engineer, from the Canadian company that drove the scheme and found that almost every country…

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  5. Alex Cannara

    logged in via LinkedIn

    Our famous Hydrogen Highway in Calif. failed, despite The Terminator's promotion, because Hydrogen is the lightest element and must be stored in some way, perhaps as hydrides, but those ways all involve energy and mass far beyond the net benefit.

    In other words, a passenger car needs about 30kW to run on a freeway. Petrol yields ~5kWHr per pound when burned. Hydrogen can yield about 14kWHr/lb, but a pound of Hydrogen is a huge weather ballon, so it must be compressed tom several thousand psi…

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    1. David Boxall

      logged in via Facebook

      In reply to Alex Cannara

      No Alex, nuclear is not part of the solution, it's just a different set of problems.

      For transport; why not take sunlight, add nutrients, carbon dioxide and biology, then let nature take its course? The result is hydrocarbons. Boring, I know, and no profit for the nuclear industry, but effective and potentially carbon-negative.

      Turning electricity into fuel for transport is loopy.

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    2. Alex Cannara

      logged in via LinkedIn

      In reply to Alex Cannara

      David, if you want a converstion, then read.

      As I said, local solar PV/hot-water (DG) is an essential part of our future, as opposed to land/resource-wasting 'farms'. This is now a focus in Calif., for example.

      Producing your "hydrocarbons" to burn means wasting most of their embedded energy, as we do now for vehicles. So, that's a non-starter. Perhaps you miss thermodynamic realities?

      The only need for combustion fuels is for those things like aircraft, that have no compact, light substitutes…

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    3. John Bailo

      logged in via Facebook

      In reply to Alex Cannara

      Poppycock.

      Northern Europe has already built a hydrogen highway and is taking delivery of production model KIA FCVs in 2013.

      What people don't understand is the US already produces enough Hydrogen to power 110 million vehicles. This hydrogen is used to boost octane in gasoline.

      Get it? We are already running our cars on the Hydrogen bonds from boosted gasoline which by itself cannot run a modern car!!!

      So the next step is ditch the substrate and use the H2 directly. In a fuel cell.

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  6. Ian L. McQueen

    Retired

    An attempt is being made to establish a "Hydrogen Village" on the Canadian province-island of Prince Edward Island. All sorts of idealistic proposals were to be incorporated (at least as far back as 2005), but the project has been scaled back and it is still not really working. The idea was to produce hydrogen from sea water using electricity from wind turbines set up on a windy cape of the island and then use the hydrogen for heating, powerng vehicles and fishing boats, etc.,etc. The last I heard…

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    1. Felix MacNeill

      Environmental Manager

      In reply to Ian L. McQueen

      Ian, I'm so glad you're here to point out to us that 'there is zero verifiable proof of a relationship beytween the gas and global temperature or climate' - otherwise we'd be indanger of being taken in by obviously amateur bodies like the Royal Society, The National Academy of Science, CSIRO, Bureau of Meteorology, etc.

      It's also great that you can remind us that the vast paleoclimatic record is actually nothing but a computer model - I'd been suffering under the delusion that computers were invented in the twentieth century, but obviously protean amoebas invented them somewhere back in the primordial slime and all data from the past must be based on readouts from those mighty ur-computers.

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    2. David Boxall

      logged in via Facebook

      In reply to Ian L. McQueen

      Ian L. McQueen: "... there is zero verifiable proof ...". It comes down to credibility.

      I've looked at climate science and come to the conclusion that I have no hope of living long enough to come to grips with it. I'm left, therefore, to decide who to believe.

      On one hand, there's every reputable body of scientists and the vast majority of scientists who are best qualified in climate science. On the other hand, there's a Canadian retiree.

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    3. Timothy Varday

      Student

      In reply to Ian L. McQueen

      "there is no need to reduce "carbon (dioxide) emissions" because there is zero verifiable proof"

      Regardless of whether there is a relationship with CO2 emissions and the warming of the earths atmosphere, it doesn't require a genius to look at some of the large cities that get chocked by pollution. Take the Beijing smog crippling the city earlier this month as an example. How many deaths were attributed to this pollution? Even if we believe your stance, I would certainly like to see a future of cities with clean skies and normal visibility.

      So even if your a climate change denier on the global warming issue, don't try and discredit the science and be against change to improve the immediate environment.

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    4. Alex Cannara

      logged in via Facebook

      In reply to Timothy Varday

      Just FYI, discussion with a expert in Chinese energy and pollution costs described yesterday how current air pollution in China creates healthcare costs of >4% of Chinese GDP, and kills ~700,000 Chinese people yearly.

      That's all San Franciscans wiped out each year. Ok, so that frees up some prime Marina housing, but still...

      The absurdity of arguments like Ian's will not prevent folks like him from being first in line for handouts, when their ignorance eventually bears distasteful fruit.

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    5. Alex Cannara

      logged in via Facebook

      In reply to Ian L. McQueen

      You're late to the party, as usual, Ian -- the "hydrogen highway" went out here even before Schwarzenegger got in with their maid.
      ;]

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  7. Tim Benham

    Student

    Is there evidence that fuel cells using hydrogen from electrolysis is competitive with using the electricity to charge batteries? Everything I have read says the contrary: fuel cell powered vehicles are more expensive to build and to run than battery electric. The article doesn't propose any other source of hydrogen apart from an allusion to biological photosynthesis, which does not produce hydrogen.

    As to ammonia, how does the author propose making it? currently ammonia is produced by the Haber-Bosch process from hydrogen which is sourced from fossil fuels. If the hydrogen were produced by electrolysis once again it is unlikely to be competitive with battery electric.

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    1. Alex Cannara

      logged in via LinkedIn

      In reply to Tim Benham

      You are right, Tim. Calling something a "cell" doesn't mean it's efficient. Fuel cells engage chemical reactions to generate heat to generate electrictiy.

      Charge/recharge of standard batteries can be over 90% efficient, just as electric motors/generators are.

      Combustion for power/propulsion makes no sense, except for aircraft/rockets, etc.

      The 'famous' Bloom Box" here in Calif. is a fuel cell system that burns natural gas to amek electricity at maybe 50% efficient. A combined-cycle fossil or nuclear plant beats that easiy. Advanced nuclear's higher temps beat the best combustion plants, whether combined or Brayton cycle.

      Any system running over 700C can break H2O & CO2 apart to make ammonia or any hydrocarbon we wish. That's what Gen-IV reactors are capable of.

      .

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    2. John Bailo

      logged in via Facebook

      In reply to Tim Benham

      Nonsense. The car body and drive train and motor are exactly the same.

      The inefficiency of the battery is that storage is proportionate to its heavy weight. Add in lossy nature of batteries and fuel cells become the obvious answer.

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    3. In reply to Tim Benham

      Comment removed by moderator.

    4. Tim Benham

      Student

      In reply to John Bailo

      @John Bailo

      "The car body and drive train and motor are exactly the same."

      I don't know what remark of mine this is in reference to,

      "The inefficiency of the battery is that storage is proportionate to its heavy weight."

      Energy storage being proportionate to weight is a common feature of all fuels.

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  8. David Noel

    Researcher

    There is a lot of sense in this article. Another, different, look at the same topic is at:

    The HydroSolar package - The complete answer to concerns about energy shortages, oil crises, greenhouse gases, global warming, power station pollution, and environmental headaches? (http://www.aoi.com.au/bcw/HydroSolar.htm).

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    1. Alex Cannara

      logged in via LinkedIn

      In reply to David Noel

      Why does the head of an institute have an aol address?

      This ignores what I tried to convey from real science above -- thermodynamics of combustion of anything is very inefficient.

      Piping combustible gas around the world is very energy intensive & dangerous -- remember our 8 San Bruno folks burned to death by our utility PG&E a couple of years ago? Remember the explosions in refineries in Calif. & Texas this year? Ever investigated pipeline deaths around the world each year.?

      Yes, solar…

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  9. Zvyozdochka

    logged in via Twitter

    The hydrogen promise has elluded people for decades and probably been driven by an obsessive-compulsive disorder most obvious in the German peoples actually.

    Methanol would be a more sensible energy storage; most of our infrastructure around cars and trucks, refueling etc could be used with little modification. Methanol could be a feedstock to aircraft fuels as well.

    There's an abundance of information on methanol-economy proposals - all less technically challenging than worrying about hydrogen.

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    1. Paul Moonie

      PhD student, solar energy

      In reply to Zvyozdochka

      Zvyozdochka, not sure if you've read the article properly mate.

      If you have any hydrogen<-->methanol fuel questions, let everyone else know!

      Cheers,
      Paul

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    2. Zvyozdochka

      logged in via Twitter

      In reply to Zvyozdochka

      @ Paul Moonie

      Is you comment necessary?

      The author appears to me to be suggesting Australia should spend money on the hydrogen-economy. I don't think there's much more to learn about creating or using it. There is a major lesson yet to be admitted however; that it's difficult and expensive, and we would essentially replace almost all of our liquid fuel transport infrastructure.

      How will we fly our aircraft on hydrogen gas energy storage? We can't.

      My comment is that it would be unecessary if we aimed for (renewable powered) synthesis of liquid hydrocarbon fuels instead however .... Like this;

      http://www.nrl.navy.mil/media/news-releases/2012/fueling-the-fleet-navy-looks-to-the-seas

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    3. aligatorhardt

      logged in via Twitter

      In reply to Zvyozdochka

      The costs of methanol production and the land and water uses limit the amount of methanol for transportation. We can use the additional help from hydrogen. Hydrogen used in fuel cells for EV cars can be emission free both in gas production and vehicle operation. For ships, sourcing hydrogen from water is the ultimate efficient fuel. We can use all transportation options for replacing petroleum. Hydrogen produced by electrolysis using off peak production from wind and solar power is also a good way to provide power storage in the form of a readily dispatched fuel, which can be used in backup generators for low wind and solar production times, or sold as transportation fuel. http://www.greencarcongress.com/2011/11/tmc-20111115.html#more

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  10. aligatorhardt

    logged in via Twitter

    I have seen many articles about the use of polymer coated carbon nanotube catalyzers that produce hydrogen at lower cost than platinum catalixers. This advancement is not mentioned here. Hydrogen technology so far has mostly been using natural gas as the source of hydrogen, but the best course of study is to source hydrogen from water. That is the truly clean and ultimately sustainable way to obtain hydrogen. http://www.renewableenergymagazine.com/article/hydrogenfuelled-power-cruiser-highlight-at-cannes-20120910

    http://www.greencarcongress.com/2011/05/egas-20110513.html#more

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